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The Influence of Hydrogen Bond on the Structure and IR Spectrum of Triphenyl Phosphite

Authors: Babkov L. M., Davydova N. A., Ivlieva-Peretokina I. V.

Background and Objectives: The IR spectra of triphenyl phosphite (TPP) have been measured at temperatures of 12 and 320 K in five phase states: crystalline (monoclinic and hexagonal phases), “glacial”, amorphous and liquid. It is necessary to clarify the effect of hydrogen bonding on the structure and IR spectrum of TPP. Materials and Methods: The IR spectra were measured on the IFS-88 spectrophotometer using the OPUS software. The spectral resolution was 2 cm^(-1).

IR Spectra of Salol and theirs Interpretation by Molecular Modeling

Authors: Babkov L. M., Davydova N. A., Ivlieva I. V.

IR spectra of salol have been measured at stable and metastable phases at temperature range from 11 to 298 K. IR spectra are different. We suggest that conformational mobility of salol and influence of H-bonding are responsible for the differences.